Recrystallization: Good ideas!
- Never, Never, Never Never, Never, Never boil the solution containing your
product to dryness. This technique accomplishes nothing since impurities and
product remain trapped together at the bottom of the flask.
- If you have added too much solvent, boil it away over an appropriate heating
source (no flames!) but don't boil it to dryness!
- If crystals refuse to appear use a stirring rod to scratch the interior surface
of the flask. This technique will often encourage seed crystals to leave the
wall of the flask and initiate recrystallization.
- Use an Erlenmeyer flask, not a beaker, for recrystallization attempts. The
flask's smaller opening reduces the amount of solvent that escapes during heating.
(Note that this isn't an advantage if you've added too much solvent and now must
boil some away!)
- Place a small glass stirring rod in the recrystallization flask to serve as
a boiling chip. Failure to do this may result in uncontrolled boiling, splashing
and loss of product.
- Use an ice/water bath to cool the recrystallization mixture only after the
mixture has slowly cooled to room temperature. Be sure to properly support the
recrystallization flask so that it doesn't tip over, fill with water and ruin
your day.
- Use the "swish and dump" technique
to
transfer your product crystals
to the Buchner funnel.